Functionalization of gold nanoparticles by β-cyclodextrin as a probe for the detection of heavy metals in water and photocatalytic degradation of textile dye

M R Bindhu; P Saranya; M Sheeba; C Vijilvani; T S Rejiniemon; Amal M Al-Mohaimeed; Mohamed Ragab AbdelGawwad; Mohamed Soliman Elshikh

doi:10.1016/j.envres.2021.111628

Functionalization of gold nanoparticles by β-cyclodextrin as a probe for the detection of heavy metals in water and photocatalytic degradation of textile dye

Environ Res. 2021 Oct:201:111628. doi: 10.1016/j.envres.2021.111628. Epub 2021 Jul 2.

Authors

M R Bindhu¹, P Saranya², M Sheeba², C Vijilvani³, T S Rejiniemon⁴, Amal M Al-Mohaimeed⁵, Mohamed Ragab AbdelGawwad⁶, Mohamed Soliman Elshikh⁷

Affiliations

¹ Department of Physics, Sree Devi Kumari Women's College, Kuzhithurai, 629163, Tamilnadu, India. Electronic address: bindhufm@gmail.com.
² Department of Physics, Sree Devi Kumari Women's College, Kuzhithurai, 629163, Tamilnadu, India.
³ Department of Physics, Government Polytechnic College, Thoothukudi, 628003, Tamilnadu, India. Electronic address: vijilvani@gmail.com.
⁴ Department of Botany and Biotechnology, AJ College of Science and Technology, Thonnakal, Trivandrum, India.
⁵ Department of Chemistry, College of Science, King Saud University, P.O. Box 22452, Riyadh, 11495, Saudi Arabia.
⁶ Genetics and Bioengineering, Faculty of Engineering and Natural Sciences, International University of Sarajevo, 71210, Sarajevo, Bosnia and Herzegovina.
⁷ Department of Botany and Microbiology, College of Science, King Saud University, P.O. Box 22452, Riyadh, 11495, Saudi Arabia.

PMID: 34224705
DOI: 10.1016/j.envres.2021.111628

Abstract

Gold nanoparticles (AuNPs) and AuNPs functionalized by β-cyclodextrin (β-CD/AuNPs) were prepared successfully through chemical reduction method. The structural, morphological, optical, compositional and vibrational studies for the AuNPs and β-CD/AuNPs were carried out. Functionalization of AuNPs by β-CD was confirmed with FT-IR results. The UV-visible absorption spectra exhibit a red-shift with decreasing average particle size. This sustains the enhancement in surface area (SA) to volume (V) ratio that is one of the peculiar characteristics of nanoparticles. TEM results show that β-CD/AuNPs formed were monodispersed and self assembled. Also it shows a decrease in average particle size and improved distribution. The use of β-CD in the synthesis of AuNPs are revealed not only create uniform small sized nanoparticles but these water soluble nanoparticles have very good antibacterial action by inhibiting the growth of bacteria commonly found in water and sensing activity for sensing the concentration of toxic metals in water. The sensitivity of the system towards copper (Cu) concentration was found as 1.788/mM for β-CD/AuNPs and 1.333/mM for AuNPs. The photocatalytic action of the obtained nanoparticles increases with decreasing average particle size. The k_app value of this photocatalytic degradation of textile dyeing waste water in presence of AuNPs was 0.002/min and β-CD/AuNPs was 0.005/min. This is a non-toxic and eco-friendly approach.

Keywords: Copper sensor; Gold nanoparticles; Heavy metal; Photocatalyst; Textile dyeing waste water; β-Cyclodextrin.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Gold
Metal Nanoparticles*
Spectroscopy, Fourier Transform Infrared
Textiles
Water
beta-Cyclodextrins*

Substances

beta-Cyclodextrins
Water
Gold