Preparation of polyvinylidene fluoride composite ultrafiltration membrane for micro-polluted surface water treatment

Abstract

Blending modification of graphene oxide (GO) and deposition of silver carbonate (Ag₂CO₃) on the membrane surface by suction filtration was used to prepare polyvinylidene fluoride (PVDF) composite ultrafiltration (UF) membranes (denoted as PGA membranes). The effect of this strategy on the morphology and performance of the pure PVDF membrane was investigated. Owing to an increased hydrophilicity and the formation of a more open pore, the pollution resistance and permeability of the PGA membrane were improved. The pure water flux of the PGA-3 membrane (254 LMH) was increased to more than 2-fold compared to that of the neat PVDF membrane (126 LMH). In addition, the results of antifouling experiments showed that the flux recovery rate, flux decay rate, and antibacterial performance of the PGA-3 membrane was superior to those of the other membranes synthesized in this study. Finally, after conducting multi-cycle filtration experiments with lake water, the flux and recovery rate of the PGA-3 membrane was observed to be the highest, and the water quality of the lake water filtered by the PGA-3 membrane was the best. Thus, the above results indicate that this membrane modification strategy is extraordinarily effective in improving the antifouling properties and permeability of the PVDF UF membranes in practical applications.

Keywords: Antifouling; Graphene oxide; Polyvinylidene fluoride; Silver carbonate; Ultrafiltration membrane; Water treatment.