Synthesis and Structural Characterization of Graphite-Like [(Me3Sn)3O]Cl

Bodo Räke; Peter Müller; Herbert W Roesky; Isabel Usón

doi:10.1002/(SICI)1521-3773(19990712)38:13/14<2050::AID-ANIE2050>3.0.CO;2-L

Synthesis and Structural Characterization of Graphite-Like [(Me₃Sn)₃O]Cl

Angew Chem Int Ed Engl. 1999 Jul 12;38(13-14):2050-2052. doi: 10.1002/(SICI)1521-3773(19990712)38:13/14<2050::AID-ANIE2050>3.0.CO;2-L.

Authors

Bodo Räke¹, Peter Müller¹, Herbert W Roesky¹, Isabel Usón¹

Affiliation

¹ Institut für Anorganische Chemie der Universität, Tammannstrasse 4, D-37077 Göttingen (Germany), Fax: (+49) 551-39-3373.

Abstract

Two different routes were used to synthesize [(Me₃Sn)₃O]Cl, a compound which, in the solid state, has a planar AB layer structure, similar to that of graphite, as a result of cation-anion interactions (see picture).

Keywords: Layered compounds; Oxonium ions; Oxygen; Tin.