Transition metal-catalysed functionalizations of inert C-H bonds to construct C-C bonds represent an ideal route in the synthesis of valuable organic molecules. Fine tuning of directing groups, catalysts and ligands has played a crucial role in selective C-H bond (sp2 or sp3) activation. Recent developments in these areas have assured a high level of regioselectivity in C-H olefination reactions. In this review, we have summarized the recent progress in the oxidative olefination of sp2 and sp3 C-H bonds with special emphasis on distal, atroposelective, non-directed sp2 and directed sp3 C-H olefination. The scope, limitation, and mechanism of various transition metal-catalysed olefination reactions have been described briefly.
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