Over the past two decades, there has been a substantial increase in the number of synthetically useful transformations catalyzed by silver. Across the range of silver-catalyzed reactions that have been reported, dinuclear species often emerge as a common feature, either as the (pre-)catalysts themselves or as intermediates during catalysis. This Minireview explores the role of dinuclear silver complexes in homogeneous catalysis, which we hope will aid in the development of improved design principles for silver catalysts.
Keywords: homogeneous catalysis; reaction mechanisms; silver.
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