Ti3C2Tx MXene sensor for rapid Hg2+ analysis in high salinity environment

Abstract

Mercury is one of the leading chemicals of concern and receives much attention in environmental safety. It is of great necessity to develop advanced Hg²⁺ analysis method for rapid detection and monitoring. Field-effect transistor (FET) sensor, an emerging electronic sensor, has received great attention in environmental analysis since it has unique advantages in achieving rapid analysis of chemicals. Herein, an FET sensor is constructed with Ti₃C₂T_x MXene as the channel material to detect Hg²⁺ in water. The sensor displays rapid and selective response to Hg²⁺. Moreover, the sensor achieves satisfactory performance in Hg²⁺ detection in high salinity environment (1 M NaCl), which benefits its applications in real water analysis. Based on the investigation of sensing mechanism, the strong response of Ti₃C₂T_x MXene FET sensor to Hg²⁺ is due to the adsorption and reduction of Hg²⁺ to Hg⁺ on the Ti₃C₂T_x surface. This reported label-free Ti₃C₂T_x MXene platform can detect Hg²⁺ in high salinity environment with high specificity, which has significant application potential for on-site monitoring and risk assessment of Hg²⁺ in aqueous systems.

Keywords: Field-effect transistor; High selectivity; Label-free detection; Mercury ion; Ti(3)C(2)T(x) MXene.