Visual detection of viscosity through activatable molecular rotor with aggregation-induced emission

Abstract

Food safety has become one of the urgent affairs in the global public health studies, and irregular viscosity is closely associated with the food spoilage extent. In this study, one kind of activatable molecular rotor (TPA-PBZ) based on triphenylamine derivates has been synthesized via the Schiff base condensation reaction. This rotor is comprised by donor-accepter conjugated structure, with aggregation induced-emission feature and a large Stokes shift of 160 nm in water. The rotation of aromatic rings in TPA-PBZ is restricted in high-viscosity microenvironment, with the gradually increasing fluorescence emission signal at 568 nm. Significantly, this rotor TPA-PBZ has successfully been applied not only in the determination of thickening effects of food gum, but also in the detection of viscosity enhancement during the liquid food spoilage process. This molecular rotor can be utilized as an intelligent monitor platform for food quality and safety inspection in viscosity-related conditions.

Keywords: Activatable molecular rotor; Aggregation-induced emission; Fluorescence; Food spoilage; Viscosity-dependence.