High AC and DC Electroconductivity of Scalable and Economic Graphite-Diamond Polylactide Nanocomposites

Materials (Basel). 2021 May 26;14(11):2835. doi: 10.3390/ma14112835.

Abstract

Two types of graphite/diamond (GD) particles with different ash content was applied to prepare new electroconductive polylactide (PLA)-based nanocomposites. Four samples of nanocomposites for each type of GD particles with mass fraction 0.01, 0.05, 0.10, and 0.15 were prepared via an easily scalable method-melt blending. The samples were subjected to the studies of electrical properties via broadband dielectric spectroscopy. The results indicated up to eight orders of magnitude improvement in the electrical conductivity and electrical permittivity of the most loaded nanocomposites, in reference to the neat PLA. Additionally, the influence of ash content on the electrical conductivity of the nanocomposites revealed that technologically less-demanding fillers, i.e., of higher ash content, were the most beneficial in the light of nanofiller dispersibility and the final properties.

Keywords: diamond; electrical conductivity; electrical properties; graphite; nanocomposite; polylactide.