The relationship between rheological features in the absence of a magnetic field and magnetic response was investigated for κ-carrageenan magnetic hydrogels containing carbonyl iron particles. The concentration of carrageenan was varied from 1.0 to 5.0 wt%, while the concentration of carbonyl iron was kept at 70 wt%. The magnetic response revealed that the change in storage modulus ΔG' decreased inversely proportional to the carrageenan concentration. A characteristic strain γ1 where G' equals to G″ was seen in a strain range of 10-3. It was found that ΔG' was inversely proportional to the characteristic stress at γ1. Another characteristic strain γ2 where the loss tangent significantly increased was also analyzed. Similar to the behavior of γ1, ΔG' was inversely proportional to γ2. The characteristic stresses at γ1 and γ2 were distributed at 80-720 Pa and 40-310 Pa, respectively. It was revealed that a giant magnetorheology higher than 1 MPa can be observed when the characteristic stresses at γ1 and γ2 are below approximately 240 Pa and 110 Pa, respectively.
Keywords: carrageenan; magnetic gel; magnetorheologylogy; stimuli-responsive material; viscoelastic property.