Sustainable preparation of bifunctional cellulose nanocrystals via mixed H2SO4/formic acid hydrolysis

Carbohydr Polym. 2021 Aug 15:266:118107. doi: 10.1016/j.carbpol.2021.118107. Epub 2021 Apr 24.

Abstract

In this work, a sustainable and highly efficient approach for preparing bifunctional cellulose nanocrystals (CNCs) was proposed through a mixed acid system of sulfuric acid and formic acid (FA). It was found that low-concentration (5-10 wt%) sulfuric acid can significantly improve the hydrolysis efficiency of FA (65-80 wt%), which enabled the highly efficient preparation of CNCs, i.e., the maximum yield of CNCs reached up to 70.65%. The obtained CNCs exhibited a rod-like shape with high crystallinity, and good dispersibility in both water and some organic phases. Moreover, the as-prepared CNCs exhibited high thermal stability, which is much higher than that of the traditionally sulfuric acid hydrolyzed ones. In addition, it was demonstrated that the bifunctional CNCs were able to stabilize various oils to form stable Pickering emulsion gels. Thus, this work provides a promising approach for sustainable preparation of bifunctional CNCs, which may find high-end applications in diverse fields.

Keywords: Cellulose nanocrystals; Mixed acid hydrolysis; Organic acid hydrolysis; Pickering emulsion; Surface functionality.