Bridging (Thionylimido)metal Complexes

Liam J R McGeachie; Michael Bühl; David B Cordes; Alexandra M Z Slawin; J Derek Woollins

doi:10.1021/acs.inorgchem.1c00725

Bridging (Thionylimido)metal Complexes

Inorg Chem. 2021 Jun 21;60(12):8423-8427. doi: 10.1021/acs.inorgchem.1c00725. Epub 2021 May 27.

Authors

Liam J R McGeachie¹, Michael Bühl¹, David B Cordes¹, Alexandra M Z Slawin¹, J Derek Woollins^{1

2}

Affiliations

¹ EaStCHEM School of Chemistry, University of St. Andrews, St. Andrews, Fife KY16 9ST, United Kingdom.
² Department of Chemistry, Khalifa University, Abu Dhabi, United Arab Emirates.

PMID: 34043915
DOI: 10.1021/acs.inorgchem.1c00725

Abstract

We report the first examples of the thionylimido ligand acting as a μ₂-bridging ligand between two transition-metal centers; using Cp₂Ti(NSO)₂, we describe bi- and tetrametallic systems.