Studies were carried out on the impact of UV radiation contact time and UV/chlorination processes on changes in polycyclic aromatic hydrocarbons (PAHs) content in treated wastewater in order to obtain environmentally safe water. The research showed that the optimal time of UV irradiation for both processes was 30 min. After irradiation, the total concentration of PAH decreased by 66%, and after the UV/chlorination process by 78%. Following UV irradiation, the reduction ranged from 74% to 81% for 3-ring PAHs, 4-ring benzo(a)anthracene and 5-ring dibenzo(a,h)anthracene. Using the UV/chlorination process, the greatest changes were observed for acenaphthene (93 ± 4%), anthracene (90 ± 4%), pyrene (87% ± 3) and acenaphthylene (83 ± 4%). Due to limited information on the mechanisms which can be responsible for the observed decrease in PAH content in wastewater after the UV and UV/chlorination processes, it cannot be clearly stated to what extent the methods used affect the actual reduction of the concentration, therefore further research is required.
Keywords: Chlorination processes; Municipal wastewater; Polycyclic aromatic hydrocarbons (PAHs); UV radiation.
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