Evaluation of the photocatalytic performance of molecularly imprinted S-TiO2 by paper microzones

Abstract

The paper microzones method (PMZs) is a green chemical method that uses the principle of the three primary colors of red, green and blue (RGB) to detect the water quality of the droplets on white paper. However, this method is rarely used in the performance evaluation of photocatalysts. The paper details the first use of paper microzones utilized in the evaluation of photocatalyst performance. A sol-gel method was used to prepare molecularly imprinted modified TiO₂ photocatalysts for the treatment of different wastewaters, and characterized the catalysts using XRD and several other methods. The reliability of PMZs on the evaluation of photocatalytic activity and selectivity was also analyzed. The following results were obtained: EP-TiO₂ catalysts (EP, ethyl paraben, the imprinting molecule) with different S doping levels were synthesized using a one-step sol-gel method, and the best S doping ratio was found to be n(Ti):n(S) 3:1. S-EP-TiO₂ was found to be 100% anatase and showed excellent photocatalytic performance, while the PMZs method accurately determined changes in RGB levels for the photocatalytic degradation process of pollutants using S-EP-TiO₂ as the photocatalyst. A photocatalytic kinetic analysis showed the PMZs method was quite suitable for the evaluation of photocatalyst activity, but the evaluation of selectivity needs improvement. This method is a promising green chemistry way to evaluate photocatalyst performance and the rapid detection of outdoor sewage water quality.

Keywords: Paper microzones; Photocatalytic; TiO(2); Wastewater.