Crystallization of carbonic acid likely begins with a linear or ribbon-esque oligomerization, but a helical spiral is shown here to be a new, competing motif for this process. The present combined density functional theory and coupled-cluster theory work examines both the ribbon and the new helical spiral motifs in terms of relative energies, sequential binding energies, and electronic spectra which could potentially aid in distinguishing between the two forms. The helix diverges in energy from the ribbon by roughly 0.2 eV (∼4 kcal/mol) per dimer addition, but the largest intensity absorption features at 9.16 eV (135 nm) and 7.11 eV (175 nm), respective of the ribbon and spiral, will allow these to be separately observed and classified via electronic spectroscopy to determine more conclusively which motif holds in the earliest formation stages of solid carbonic acid.