A novel lanthanum-modified copper tailings adsorbent for phosphate removal from water

Haiyang Jin; Li Lin; Xiaoyang Meng; Linling Wang; Zhuo Huang; Min Liu; Lei Dong; Yuan Hu; John C Crittenden

doi:10.1016/j.chemosphere.2021.130779

A novel lanthanum-modified copper tailings adsorbent for phosphate removal from water

Chemosphere. 2021 Oct:281:130779. doi: 10.1016/j.chemosphere.2021.130779. Epub 2021 May 12.

Authors

Haiyang Jin¹, Li Lin², Xiaoyang Meng³, Linling Wang⁴, Zhuo Huang¹, Min Liu¹, Lei Dong¹, Yuan Hu¹, John C Crittenden³

Affiliations

¹ Basin Water Environmental Research Department, Changjiang River Scientific Research Institute, Wuhan, Hubei, 430010, China; Key Lab of Basin Water Resource and Eco-Environmental Science in Hubei Province, Wuhan, 430010, China.
² Basin Water Environmental Research Department, Changjiang River Scientific Research Institute, Wuhan, Hubei, 430010, China; Key Lab of Basin Water Resource and Eco-Environmental Science in Hubei Province, Wuhan, 430010, China. Electronic address: linli1229@hotmail.com.
³ Brook Byers Institute of Sustainable Systems, School of Civil and Environmental Engineering, Georgia Institute of Technology, Atlanta, GA, 30332, United States.
⁴ School of Environmental Science and Technology, Huazhong University of Science and Technology, Wuhan, Hubei, 430074, China.

PMID: 34015652
DOI: 10.1016/j.chemosphere.2021.130779

Abstract

La(OH)₃-modified copper tailings were prepared, characterized, and investigated for phosphate removal from water in this study. Scanning electron microscopy (SEM) analysis showed that La(OH)₃ modification made a large amount of spherical solid agglomerates appeared on the surface of the copper tailings and created many pores. Laser particle size analysis indicated that the modified copper tailings had much a smaller particle size and larger specific surface area. Fourier Transform Infrared Spectroscopy (FTIR) and X-ray fluorescence (XRF) analysis illustrated that lanthanun was successfully loaded on the copper tailings with a mass percentage of 25.31%. The adsorption kinetics and isothermal adsorption experiment results indicated that the La(OH)₃-modified copper tailings had a much better phosphate adsorption capacity than the original copper tailings. The adsorption kinetics process of the La(OH)₃-modified copper tailings followed the pseudo-second-order kinetic model, and the isothermal adsorption data were well fitted by the Langmuir isotherm model. The maximum phosphorus adsorption capacity of the copper tailings after alkali treatment and La(OH)₃ modification increased from 737.04 mg/kg to 7078.43 mg/kg, which was close to that of Phoslock. Leaching toxicity testing demonstrated that the use of La(OH)₃-modified copper tailings for phosphorus removal in water treatment would not cause secondary pollution. Adsorption mechanism analysis revealed that both electrostatic attraction and ligand exchange were involved in phosphate adsorption onto La(OH)₃-modified copper tailings. The phosphate adsorption of La(OH)₃-modified copper tailings was pH-dependent, and a high-pH environment resulted in a decline in adsorption capacity. The increased concentration of OH^- in high-pH solution was unfavorable for ligand exchange between phosphate species and hydroxyl groups from La(OH)₂ species. In addition, competitive adsorption between HPO₄^2- and the increased amounts of OH^- weakened electrostatic attraction. The results suggested that La(OH)₃-modified copper tailings are promising adsorbents for highly efficient phosphate removal and provide a new method to realize the resource utilization of copper tailings.

Keywords: Absorption; Copper tailings; Lanthanide modification; Phosphate removal.

MeSH terms

Adsorption
Copper
Hydrogen-Ion Concentration
Kinetics
Lanthanum*
Phosphates
Spectroscopy, Fourier Transform Infrared
Water
Water Pollutants, Chemical* / analysis

Substances

Phosphates
Water Pollutants, Chemical
Water
Lanthanum
Copper