Low-cost devices with fluorescence spots brightness and size dual-mode readout for the rapid detection of Cr(VI) based on smartphones

Abstract

Sensitive, convenient and rapid detection devices for toxic Cr(VI) suitable for filed use are required. Smartphone can be used as the detector, but the quality of images taken with a smartphone may depend on the ambient light and the operator. In this work, two types of low-cost and portable smartphone-based devices used for fluorescence spots brightness and size dual-mode detection of Cr(VI) were constructed with the aid of the 3D printing, which avoids the effect of ambient light and maintains a fixed position of the phone camera relative to the samples. Based on the brightness reflected by the blue channel of RGB values of the images of carbon nanodots, a linear relationship between quenching efficiency and concentration of Cr(VI) in a range of 0.2-150 μM with a limit of detection of 0.058 μM was attained, which is comparable to or better than that from fluorescence spectrometers. With the size variation of fluorescence spots, a linear range of 10-350 μM was acquired and it is more intuitive for direct naked-eye estimation of the concentration of Cr(VI). The applicability of the proposed devices for the detection of Cr(VI) was verified with water and soil samples with recoveries ranging in 95.0-108.2%.

Keywords: Carbon nanodots; Cr(VI) sensing; Dual-mode sensing; Smartphone-based devices; Visualization.