Carbon nanotube functional materials (CNTFMs) represent an important research field in transforming nanoscience and nanotechnology into practical applications, with potential impact in a wide realm of science, technology, and engineering. In this review, we combine the state-of-the-art research activities of CNTFMs with the application prospect, to highlight critical issues and identify future challenges. We focus on macroscopic long fibers, thin films, and bulk sponges which are typical CNTFMs in different dimensions with distinct characteristics, and also cover a variety of derived composite/hierarchical materials. Critical issues related to their structures, properties, and applications as robust conductive skeletons or high-performance flexible electrodes in mechanical and electronic devices, advanced energy conversion and storage systems, and environmental areas have been discussed specifically. Finally, possible solutions and directions are proposed for overcoming current obstacles and promoting future efforts in the field.
Keywords: CNT fibers; CNT films; CNT sponges; carbon nanotubes; freestanding electrode; functional materials; hierarchically porous; van der Waals heterojunction.