Haiyang-1C (HY-1C) is the first operational ocean color satellite of China, which is intended to obtain daily global ocean color data. The Ultraviolet Imager (UVI) onboard provides a potential novel detector for the detection of marine oil spills. Although airborne UV sensors have shown great efficiency for the detection of spilled oils, the capability of spaceborne UV sensor is not yet clear. In this study, we designed a ground-based experiment to interpret the UV characteristics of various weathered oils, and found that very thin oil films are quite sensitive to the UV radiation due to the surface interference light. Moreover, by comparing spaceborne and airborne UV images of spilled oils collected from HY-1C UVI and AVIRIS, the scale effect of ultraviolet remote sensing has been interpreted clearly. The interference light and sunglint reflection play different roles in the imaging process of spilled oils, leading them to appear radical different features (brighter or darker than the background oil-free seawater) in ground, airborne and spaceborne observation, which deserves further research. Ultraviolet remote sensing, therefore, can work as a new approach and improve the detection and monitoring of marine oil spills.