Faradic capacitive deionization (FCDI) for desalination and ion removal from wastewater

Abstract

Capacitive deionization (CDI) is one of the emerging desalination technologies that attracted much attention in the last years as a low-cost, energy-efficient, and environmentally-friendly alternative to other desalination technologies, such as multi-stage flash desalination (MSF) and multiple effect distillation (MED). The implementation of faradaic electrode materials is a promising method for enhancing CDI systems' performance by achieving higher salt removal characteristics, lower energy consumption, and better ion selectivity. Therefore, a novel CDI technology named Faradaic CDI (FCDI) that implements faradaic electrode materials arose as a high-performance CDI cell design. In this work, the application of FCDI cells in desalination and wastewater treatment systems is reviewed. First, the progress done on using various FCDI systems for saline water desalination is summarized and discussed. Next, the application of FCDI in wastewater treatment applications and selective ion removal is presented. A thorough comparison between FCDI and conventional carbon-based CDI is carried out in terms of working principle, electrode material's cost, salt removal performance, energy consumption, advantages, and disadvantages. Finally, future research consideration regarding FCDI technology is included to drive this technology closer towards practical application.

Keywords: Asymmetric dual-ion FCDI cells; Faradaic battery electrodes; Faradic capacitive deionization (FCDI); Symmetric dual-ion FCDI cells; Wastewater treatment; Water desalination.