Cu2Se nanowires shelled with NiFe layered double hydroxide nanosheets for overall water-splitting

Hongyun Qi; Peng Zhang; Haiyan Wang; Yongmei Cui; Xien Liu; Xilin She; Yonghong Wen; Tianrong Zhan

doi:10.1016/j.jcis.2021.04.101

Cu₂Se nanowires shelled with NiFe layered double hydroxide nanosheets for overall water-splitting

J Colloid Interface Sci. 2021 Oct:599:370-380. doi: 10.1016/j.jcis.2021.04.101. Epub 2021 Apr 21.

Authors

Hongyun Qi¹, Peng Zhang¹, Haiyan Wang¹, Yongmei Cui¹, Xien Liu¹, Xilin She², Yonghong Wen¹, Tianrong Zhan³

Affiliations

¹ Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science (Ministry of Education), State Key Laboratory Base of Eco-chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China.
² School of Environmental Science and Engineering, Collaborative Innovation Center for Marine Biomass Fiber, Materials and Textiles of Shandong Province, Qingdao University, Qingdao 266071, China.
³ Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science (Ministry of Education), State Key Laboratory Base of Eco-chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China. Electronic address: trzhan@qust.edu.cn.

PMID: 33962198
DOI: 10.1016/j.jcis.2021.04.101

Abstract

It is imperative but challenging to develop non-noble metal-based bifunctional electrocatalysts for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER). Our work reports a core-shell nanostructure that is constructed by the electrodeposition of ultrathin NiFe-LDH nanosheets (NiFe-LDHNS) on Cu₂Se nanowires, which are obtained by selenizing Cu(OH)₂ nanowires in situ grown on Cu foam. The obtained Cu₂Se@NiFe-LDHNS electrocatalyst provides more exposed edges and catalytic active sites, thus exhibiting excellent OER and HER electrocatalytic performance in alkaline electrolytes. This catalyst needs only an overpotential of 197 mV for OER at 50 mA cm^-2 and 195 mV for HER at 10 mA cm^-2. Besides, when employed as a bifunctional catalyst for overall water-splitting, it requires a cell voltage of 1.67 V to reach 10 mA cm^-2 in alkaline media. Furthermore, the corresponding water electrolyzer demonstrates robust durability for at least 40 h. The excellent performance of Cu₂Se@NiFe-LDHNS might be ascribed to the synergistic effect from the ultrathin NiFe-LDHNS, the Cu₂Se nanowires anchored on the Cu foam, and the formed core-shell nanostructure, which offers large surface area, ample active sites, and sufficient channels for gas and electrolyte diffusion. This work provides an efficient strategy for the fabrication of self-supported electrocatalysts for efficient overall water-splitting.

Keywords: Bifunctional electrocatalyst; Core-shell structure; Cu(2)Se nanowires; NiFe layered double hydroxide nanosheets; Water-splitting.