Metal nanoparticles have been widely used for improving the efficiencies of many optoelectronic devices. Herein, position effects of gold nanoparticles (Au NPs) on the performance of perovskite light-emitting diodes (PeLEDs) are investigated. Amphiphilic Au NPs are synthesized so that they can be incorporated into different layers of the PeLEDs to enhance device efficiencies. The photoluminescent (PL) studies indicate apparent position effects; the strongest PL intensity occurs when the NPs are directly blended with the light-emitting perovskite layer. In contrast, the PeLEDs exhibit the highest luminance efficiency while the Au NPs are placed in the hole-transporting layer. The direct blending of the NPs in the perovskite layer might affect the electrical properties, resulting in inferior device performance. The results reported herein can help to understand the enhancing mechanism of the PeLEDs and may also lead to even better efficiencies in the near future.
Keywords: electroluminescence; nanoparticle; perovskite; photoluminescence; plasmonics.