A vinyl-functionalized all-cis-tetrasiloxycyclotetrasiloxane [ViSi(OSiMe2H)O]4 (Vi = vinyl group) Janus precursor was prepared from potassium cyclotetrasiloxane silanolate. The Janus precursor was selectively modified at its dimethylhydrosilyl groups [-SiMe2H] via the Piers-Rubinsztajn reaction to obtain a family of new tetravinyl-substituted Janus rings [ViSi(OR')O]4 containing various functional groups in moderate yields. Remarkably, the tetravinyl groups on the structure remained intact after modification by the Piers-Rubinsztajn reaction. Since these synthesized compounds possess multiple functional groups (up to eight per molecule), they are potential precursors for advanced hybrid organic-inorganic functional materials.
Keywords: Janus ring; Piers–Rubinsztajn reaction; cyclotetrasiloxane; hybrid organic-inorganic; silsesquioxane; vinyl monomer.