Field investigations have proved that frozen soil does not act as a completely impermeable barrier for contaminants in cold regions. However, the subsurface behaviors of solutes in freezing and frozen porous media are still unclear. To unveil their nature, the pore-scale behavior of potassium permanganate in saturated porous media subjected to the unidirectional freezing was investigated using micromodel visualizations. An optical microscope was applied to obtain the pore-scale kinetics of solute redistribution in a two-dimensional micromodel using a calibration curve between the color intensity and concentration. We found that (1) the solute migration was not only limited to the ice-water interface but also occurred in the freezing area; (2) the redistribution of solutes had a significant hysteresis effect relative to the freezing front movement during the freezing of the porous media. By combining these results with the theory of sea ice, we suggested that the formation and re-motion of solute-rich inclusions in the mushy layer appear to be vital processes responsible for these phenomena. It was believed that the major mechanism for the re-motion of liquid inclusions was brine diffusion and expulsion in this experiment. The results of this study provide a better understanding of the physics of contaminant migration and their complex kinetics at the pore scale, which has important implications for the assessment and remediation of contaminated soils in seasonal frozen soils and permafrost.
Keywords: Brine channels; Micromodels visualization; Pre-melting; Solute redistribution; Unidirectional freezing.
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