Stack Thermo-Osmotic System for Low-Grade Thermal Energy Conversion

ACS Appl Mater Interfaces. 2021 May 12;13(18):21371-21378. doi: 10.1021/acsami.1c03395. Epub 2021 Apr 27.

Abstract

Thermo-osmotic energy conversion (TOEC) technology, developed from membrane distillation, is an emerging method that has the potential of obtaining electricity efficiently from a low-grade heat source but faces the difficult problem of pump power loss. In this study, we build a novel TOEC system with a multistage architecture that can work without pump assistance. The experiment system, made of cheap commercial materials, can obtain a power density of 1.39 ± 0.25 W/m2, with a heating temperature of 80 °C, and its efficiency increased linearly with the total stage number. A theory calculation shows that a 30-stage system with a specific membrane and a working pressure of 5.0 MPa can obtain an efficiency of 2.72% with a power density of 14.0 W/m2. By a molecular dynamics simulation, it is shown that a high-performance membrane has the potential to work at 40 MPa. This study proves that TOEC technology is a practical and competitive approach to covert low-grade thermal energy into power efficiently.

Keywords: hydrophobic nanoporous membranes; nanofibers; pressure-retarded membrane distillation; renewable energy; thermo-osmosis; waste heat.