Heterogeneously Ni-Pd nanoparticle-catalyzed base-free formal C-S bond metathesis of thiols

Kanju Mitamura; Takafumi Yatabe; Kidai Yamamoto; Tomohiro Yabe; Kosuke Suzuki; Kazuya Yamaguchi

doi:10.1039/d1cc00995h

Heterogeneously Ni-Pd nanoparticle-catalyzed base-free formal C-S bond metathesis of thiols

Chem Commun (Camb). 2021 Apr 21;57(31):3749-3752. doi: 10.1039/d1cc00995h. Epub 2021 Mar 26.

Authors

Kanju Mitamura¹, Takafumi Yatabe, Kidai Yamamoto, Tomohiro Yabe, Kosuke Suzuki, Kazuya Yamaguchi

Affiliation

¹ Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan. kyama@appchem.t.u-tokyo.ac.jp yatabe@appchem.t.u-tokyo.ac.jp.

PMID: 33876120
DOI: 10.1039/d1cc00995h

Abstract

This study rationally designed a heterogeneously catalyzed system (i.e., using Ni-Pd alloy nanoparticles supported on hydroxyapatite (Ni-Pd/HAP) under an H₂ atmosphere) achieving an efficient base-free formal C-S bond metathesis of various thiols via suppression of the Ni catalysis deactivation.