Previously, we showed the weight average molecular weight (M w) and intrinsic viscosity ([ƞ]) of pectic hydrocolloids recovered from steam-exploded citrus peel were low, suggesting fragmentation due to process temperature and/or time-at-temperature. We have tested this hypothesis on a commercial lime pectin peel, washed to remove soluble sugars and dried for stabilization, using a static steam explosion system. We examined temperatures of 120-150°C at 1-3 min hold times. Galacturonic acid recovery and M w ranged from 22% to 82% and 142-214 kDa, respectively. Recovery of most major pectic sugars increased concomitantly with galacturonic acid as temperature and time-at-temperature increased. [ƞ] ranged from 1.75 to 6.83 dl/g. The degree of methylesterification ranged from 66.5% to 72.1%. Tan (δ) (Loss modulus/Storage modulus; G″/G') values of sugar-acid gels for 120-140°C treatments were <1.0. Ideal optimization analysis, where time, [ƞ], and percent recovery were maximized, identified processing conditions that favor either increased [ƞ] or percent recovery. The results presented here support our hypothesis that temperature and time-at-temperature affect M w and [η] of the recovered pectic hydrocolloids. These results also demonstrate that manipulating either temperature or time-at-temperature enables the production of structurally varied populations of pectic hydrocolloids. Based on optimization analysis, commercially viable values of [ƞ] can be obtained while recovering approximately 50% of the pectic hydrocolloids.
Keywords: citrus; hydrocolloid; intrinsic viscosity; pectin; recovery; steam explosion.
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