We probe the high frequency emission of a carbon nanotube based Josephson junction and compare it to its dc Josephson current. The ac emission is probed by coupling the carbon nanotube to an on-chip detector (a superconductor-insulator-superconductor junction), via a coplanar waveguide resonator. The measurement of the photoassisted current of the detector gives direct access to the signal emitted by the carbon nanotube. We focus on the gate regions that exhibit Kondo features in the normal state and demonstrate that when the dc supercurrent is enhanced by the Kondo effect, the ac Josephson effect is strongly reduced. This result is compared to numerical renormalization group theory and is attributed to a transition between the singlet ground state and the doublet excited state which is enabled only when the junction is driven out-of-equilibrium by a voltage bias.