Spectroscopy of transient anions and radicals by gated and accelerated time-of-flight experiment is a new spectrometer developed in UCLouvain. This instrument measures high-resolution photodissociation spectra of mass-selected ions by the combination of a time-of-flight spectrometer including a specific gating, bunching, and re-referencing unit with a nanosecond pulsed dye laser, a pulsed deflection, and an energy selector. The ionic species are generated in a supersonic jet expansion by means of an electric discharge or by the impact of electrons coming from an electron gun. The versatility of the molecular systems that can be addressed by this instrument is illustrated by the presentation of mass spectra of cations, anions, and ionic clusters formed from different gas mixtures and backing pressures. The high-resolution spectrum of the A~2Σ+(002)←X~2Π3/2(000) and A~2Σ+(002)←X~2Π1/2(000) rovibronic bands of N2O+ has been measured and analyzed to provide refined molecular parameters in the A~2Σ+(002) upper state. The A~2Σ+(002)←X~2Π3/2(000) band has been used to evaluate the quality of the experimental setup in terms of rotational temperature, time of measurement for certain signal to noise ratio, and the accuracy of the determination of the wavenumber scale.