Co-transport of ball-milled biochar and Cd2+ in saturated porous media

Abstract

The combination of ball milling technology and biochar materials provides new prospects for environmentally friendly and sustainable environmental pollution control technologies, but comes with opportunities and risks. In this study, column experiments were used to evaluate the environmental behavior of ball‑milled biochar (BMBC). The results of the column experiments showed that BMBC transport increased with a high flow velocity, large medium size, high pH, and low ionic strength. Owing to the strong adsorption of Cd²⁺ by BMBC, the presence of BMBC in the medium led to a decrease in effluent Cd²⁺. The presence of Cd²⁺ in the solution slightly inhibited the transport of BMBC. The transport of Cd²⁺ was facilitated by BMBC due to the high affinity. Therefore, attention should be paid to favorable conditions for BMBC transport. This study provides a perspective to assess the behavior of BMBC in the environment and whether its interaction with Cd²⁺ will introduce new environmental hazards.

Keywords: Ball‑milled biochar; Cd(2+); Porous media; Transport behavior.