The adsorption process is widely used for the treatment of wastewater containing organic pollutants. We fabricated highly branched pillar[5]arene-based porous aromatic frameworks (PAFs), PAF-P5, for the adsorption and removal of organic pollutants (short-chain alkyl derivatives 1-3 and pesticide molecules 4-6) from water with high removal efficiency (RE). However, PAF-P5 was incapable of adsorbing aromatic organic dyes 7-9. Adsorption kinetic studies indicated that the adsorption is mainly driven by strong host-guest interactions between 1-3 and the pillar[5]arene units in PAF-P5, while 4-6 only weakly interacted with the pillar[5]arene units in PAF-P5. Moreover, chemically breaking down the pillar[5]arene rings in PAF-P5 caused changes in the pore size, the microenvironment inside of the pores, and the frame morphology, and the resultant frameworks, PAF-DeP5, exhibited poor adsorption toward 1-6 but adsorbed 7-9 possibly through physical adsorption as implied by fitting the experimental data into the adsorption kinetic models.
Keywords: organic dyes; organic pollutant adsorption; pesticides; pillar[n]arenes; porous aromatic frameworks; wastewater treatment.