The degree of substitution (DS) of cellulose derivative is significantly associated with its properties. In this paper, a series of quaternary cellulose (QC) samples with different DS (ranging from 0.16 to 0.51) were synthesized with assistance of microwave and their relationship with strength improvement of fiber networks was investigated systematically. QCs were characterized by elemental analysis, FT-IR, 1H NMR, and TGA, etc. The results showed that the cationic quaternary ammonium salt group was successfully grafted onto the backbones of cellulose chains and the thermal stability was associated inversely with the DS of QCs. However, the results of strength test for the fiber networks from secondary fiber of old corrugated containers showed that the tensile and burst strength was enhanced by addition of QCs, and their performance was positively correlated their DS. The best result achieved in this investigation was in the case of QC with DS of 0.51, with increments of tensile and burst strength 6.17% and 11.68%, respectively, at a dosage of 1.0 wt% based on oven-dry pulp. This investigation highlights the importance of DS of QC to its application in strength improvement for fiber networks.
Keywords: Degree of substitution; Fiber networks; Quaternary cellulose.
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