Simultaneous removal of harmful anions from geothermal waters using OH- intercalated Mg-Fe-LDH: batch and field column studies

Abstract

Unlike collectively treatable industrial wastewaters where only one or a few pollutants have concentrations much higher than the relevant standards, geothermal waters, in which multiple harmful constituents coexist, are usually discharged dispersedly, provoking a big challenge for their effective treatment. Here, a Mg/Fe layered double hydroxide with OH^- intercalated (Mg-Fe-OH-LDH) was synthesized in a mechanochemical way and then applied in the treatment of various types of high-temperature geothermal waters in western Yunnan (China) containing a variety of harmful anions (As, Sb, W, and F) and inducing local environmental pollution. Due to the endothermic nature of removal of aqueous As, Sb, W, and F by Mg-Fe-OH-LDH, the original high temperatures of the geothermal waters could promote their sorption effectively. Batch sorption experiments demonstrated that over 94% and 80% of the As and W removal amounts could be reached within the first 10 and 20 min, respectively. On-site column experiments confirmed that the sorbent could remove the targeted harmful constituents from the investigated geothermal waters efficiently. In fact, the performance of the sorbent in the column studies was even better than that in the batch experiments, which can be ascribed to the continuous impetus for sorption caused by the concentration gradient in the flowing sorption system. Specifically, Mg-Fe-OH-LDH displayed the best sorption performance for As(V) among various harmful constituents, and the sorption of As along with W and F was little affected by the coexisting common anions in the geothermal waters, including Cl^-, SO₄^2-, and HCO₃^-/CO₃^2-. In contrast, the removal of Sb(V) from geothermal waters may be impeded to a certain extent by SO₄^2- and CO₃^2-, which possessed stronger electronegativity or smaller ionic radii. This study is the first attempt to apply Mg-Fe-LDH in treatment of geothermal waters with multiple harmful constituents and sheds a light on providing a practical approach for field treatment of geothermal water-derived pollution.

Keywords: Field column study; Geothermal water; Harmful anions; LDH; Sorption.