Integration of environmental and economic performance of Electro-Coagulation-Anodic Oxidation sequential process for the treatment of soluble coffee industrial effluent

Izabela Dobrosz-Gómez; Miguel-Ángel Gómez-García

doi:10.1016/j.scitotenv.2020.142818

Integration of environmental and economic performance of Electro-Coagulation-Anodic Oxidation sequential process for the treatment of soluble coffee industrial effluent

Sci Total Environ. 2021 Apr 10:764:142818. doi: 10.1016/j.scitotenv.2020.142818. Epub 2020 Oct 8.

Authors

Izabela Dobrosz-Gómez¹, Miguel-Ángel Gómez-García²

Affiliations

¹ Departamento de Física y Química, Facultad de Ciencias Exactas y Naturales, Universidad Nacional de Colombia, Sede Manizales, Campus La Nubia, km 9 vía al Aeropuerto la Nubia, Apartado Aéreo 127, Manizales, Caldas, Colombia. Electronic address: idobrosz-gomez@unal.edu.co.
² Departamento de Ingeniería Química, Facultad de Ingeniería y Arquitectura, Universidad Nacional de Colombia, Sede Manizales, Campus La Nubia, km 9 vía al Aeropuerto la Nubia, Apartado Aéreo 127, Manizales, Caldas, Colombia.

PMID: 33757242
DOI: 10.1016/j.scitotenv.2020.142818

Abstract

This study examined a sequential Electro-Coagulation-Anodic Oxidation (EC-AO) process, using low-cost electrodes (EC: iron/stainless steel and AO: graphite/stainless steel), as an alternative for the treatment of soluble coffee industrial effluent (a complex mixture of organic macromolecules). Process operational parameters were optimized using experimental design, ANOVA, the response surface methodology, and a constrained nonlinear optimization algorithm. Experimental results allow discussing the role of graphite electrode, the mineralization via hydroxyl radicals and chlorine species (mainly as HClO and ClO^- as defined from pH conditions and equilibrium calculations). EC-AO treatment allows achieving ca. 97% decolorization, as well as 72% and 65% of COD and TOC removal, respectively, with total operation costs of 10.81 USD/m³. The Molecular Weight Distribution (MWD) analysis showed that during the EC step, contaminants with molecular weight > 30 kDa were effectively decomposed. In contrast, AO was quite efficient in the mineralization of contaminants with MW in the range of 5 to 10 kDa. A kinetic analysis of EC-AO allowed defining the operation time of ca. 160 min required to meet permissible discharge limits for soluble coffee effluents, established by Colombian legislation; and obtaining COD and TOC degradation rate laws for upcoming studies on process conceptual design. Finally, the EC-AO process yielded an oxidized (AOS = 0.687), biocompatible (BOD₅/COD = 0.41) not toxic effluent.

Keywords: Acute toxicity test; Electrochemical integrated processes; Industrial wastewater; Operation cost analysis; Soluble coffee industry.