High-resolution transmission electron microscopy observations of bastnäsite from the Maoniuping rare earth element (REE) deposit at Panxi, SW China, revealed the presence of nanoparticles in the surface of bastnäsite crystal. The nanoparticles are identified as the bastnäsite nanocrystals, with 5-30 nm in length, by energy-dispersive spectrometry and fast fourier transform patterns. This represents the first observation of bastnäsite nanoparticle in nature, confirming a new form of migration and precipitation of La and Ce in the hydrothermal fluids. Meanwhile, we herein reveal that random attachment of small bastnäsite nanoparticles during aggregation-based growth initially produces large bastnäsite nanoparticles, driven by the tectonic stress. Subsequent evolution of the random aggregation and orientation of large bastnäsite nanoparticles result in bastnäsite crystal formation, driven by the tectonic stress and inherent surface stress. This underlines the bastnäsite crystallization by random aggregation and the significant role of tectonic stress in forming the bastnäsite crystal in REE deposit.
Keywords: Bastnäsite nanoparticles; Crystal growth; Migration and precipitation; REE deposit; Rare earth element.
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