Leaching characteristics and stability assessment of sequestered arsenic in flue dust based glass

Abstract

Arsenic (As), a toxicant, present in flue dust, tailings, and mine drainages generated from mineral processing and smelting processes represents high environmental risk due to its high mobility. Around 42-50% As is found in flue dust in the form of As₂O₃. The vitrification of As results in the formation of stable inert glass material and supposed to reduce the risk of As release to the environment. In this study, a glass material produced by vitrification of As bearing flue dust via DST GlassLock™ Process was received from Dundee Sustainable Technologies, Canada and was subjected for As stability assessment using United States Environmental Protection Agency (EPA) leaching methods-1311,1312,1313,1314,1315 and 1316. The released arsenic concentration was found to be less than the recommended TCLP hazardous waste limit for arsenic i.e., 5 mg/L in most of the test conditions. The experimental data were analyzed using LeachXS Lite™, a data management software that showed the goodness of the DST GlassLock™ Process for As stabilization and safe landfill deposition of the resulting product.

Keywords: Flue dust; Leaching; Leaching environment frame assessment; Stabilization; Vitrification.