Nano-oxides washcoat for enhanced catalytic oxidation activity toward the perovskite-based monolithic catalyst

Abstract

In order to explore a superior washcoat material to give full play to the catalytic activity of perovskite active components on the monolithic catalysts, three novel types of LaCoO₃/washcoat/cordierite monolith catalysts were prepared by a facile two-step procedure which employed the cordierite honeycomb ceramic as the monolith substrate, the nano-oxides (ZrO₂, ɤ-Al₂O₃, TiO₂) as the washcoat, and the perovskite of LaCoO₃ as the active components. The blank cordierite, powdered LaCoO₃, semi-manufactured monolithic catalysts (washcoat/cordierite), and manufactured monolithic catalysts (LaCoO₃/washcoat/cordierite) were characterized by XRD, SEM, XPS, N₂ adsorption-desorption, H₂-TPR, and ultrasonic test, and their catalytic activities and catalytic stability were evaluated by the toluene oxidation test. The research results indicate that the nanoparticles coated on the cordierite substrate as the washcoat can give full play to the catalytic ability of the LaCoO₃ active components and also showed high catalytic stability. However, the catalytic properties of the monolithic catalysts vary notably with the species of nano-washcoat. Among all the catalysts, the porous honeycomb surface structure, uniform distribution, high ratio of surface adsorbed oxygen, and strong reducing ability together give the LaCoO₃/ZrO₂/cordierite monolithic catalyst the highest catalytic activity on the oxidation of toluene at low temperature, which could be attributed to the excellent interactions of perovskite and nano-ZrO₂ washcoat. Therefore, the nano-oxides, especially the nano-ZrO₂, have a broad practical application potential for toluene oxidation at low temperature as the washcoat of perovskite-based monolithic catalysts.

Keywords: Catalytic oxidation; Cordierite; Monolithic catalyst; Nanoparticles; Perovskite; Washcoat.