Metal-Free Organic Luminophores that Exhibit Dual Fluorescence and Phosphorescence Emission at Room Temperature

Abstract

Dual-fluorescent-phosphorescent compounds have attracted increasing attention in various fields, such as bio-imaging, data protection/encryption, ratiometric luminescence sensing, and white-light emission. Conventional dual-emissive compounds contain a phosphorescent organometallic complex of a precious metal, such as iridium or platinum. However, the use of precious metals in organic materials has several drawbacks. This Minireview focuses on precious-metal-free organic light-emitting materials that exhibit dual fluorescence and phosphorescence emission in the solid state at room temperature to produce bimodal steady-state emission spectra. The dual emitters presented herein are categorized into the following six compound classes: (1) difluoroboron diaroylmethanes, (2) diarylketones, (3) diarylsulfones, (4) triazines and pyrimidines, (5) fused phenazines, and (6) N-arylcarbazoles.

Keywords: fluorescence; heterocycles; phosphorescence; photochemistry; sensors.