CdS/TiO2 is a composite photocatalyst that has been studied over many years and in which electron transfer from CdS to TiO2 is believed to lead to high photocatalytic activity. However, most reports on improved activity involve hydrogen production in the presence of a sulfide reducing agent. In this study, we comprehensively examined the effects of electron transfer, hydrogen overvoltage, substrate adsorption, and the cocatalyst from relationships between hydrogen production ability and the total number of trapped electrons in the presence of various reducing agents. As a result, we clarified that the electron transfer between CdS and TiO2 does not necessarily lead to high activity. We showed that the composite photocatalyst needs to be designed for the intended purpose and that evaluating the hydrogen production ability using sacrificial reagents provides insufficient information for use in an actual environment.
© 2021 The Authors. Published by American Chemical Society.