Quality of experience (QoE) that serves as a direct evaluation of viewing experience from the end users is of vital importance for network optimization, and should be constantly monitored. Unlike existing video-on-demand streaming services, real-time interactivity is critical to the mobile live broadcasting experience for both broadcasters and their audiences. While existing QoE metrics that are validated on limited video contents and synthetic stall patterns have shown effectiveness in their trained QoE benchmarks, a common caveat is that they often encounter challenges in practical live broadcasting scenarios, where one needs to accurately understand the activity in the video with fluctuating QoE and figure out what is going to happen to support the real-time feedback to the broadcaster. In this paper, we propose a temporal relational reasoning guided QoE evaluation approach for mobile live video broadcasting, namely TRR-QoE, which explicitly attends to the temporal relationships between consecutive frames to achieve a more comprehensive understanding of the distortion-aware variation. In our design, video frames are first processed by deep neural network (DNN) to extract quality-indicative features. Afterwards, besides explicitly integrating features of individual frames to account for the spatial distortion information, multi-scale temporal relational information corresponding to diverse temporal resolutions are made full use of to capture temporal-distortion-aware variation. As a result, the overall QoE prediction could be derived by combining both aspects. The results of experiments conducted on a number of benchmark databases demonstrate the superiority of TRR-QoE over the representative state-of-the-art metrics.