A Facile One-Pot Synthesis of Hierarchically Organized Carbon/TiO2 Monoliths with Ordered Mesopores

Jürgen Schoiber; Christian Koczwara; Simon Rumswinkel; Lawrence Whitmore; Christian Prehal; Florian Putz; Michael S Elsaesser; Oskar Paris; Nicola Hüsing

doi:10.1002/cplu.202000740

A Facile One-Pot Synthesis of Hierarchically Organized Carbon/TiO₂ Monoliths with Ordered Mesopores

Chempluschem. 2021 Feb;86(2):275-283. doi: 10.1002/cplu.202000740.

Authors

Jürgen Schoiber¹, Christian Koczwara², Simon Rumswinkel¹, Lawrence Whitmore¹, Christian Prehal², Florian Putz¹, Michael S Elsaesser¹, Oskar Paris², Nicola Hüsing¹

Affiliations

¹ Dept. of Chemistry and Physics of Materials, Paris-Lodron-University of Salzburg, Jakob-Haringer-Straße 2a, 5020, Salzburg, Austria.
² Institute of Physics, Montanuniversitaet Leoben, Franz-Josef Straße 18, 8700, Leoben, Austria.

PMID: 33599102
DOI: 10.1002/cplu.202000740

Abstract

Sol-gel processing combined with soft templating and gelation-induced phase separation is very sensitive to the precursor sol composition. In this work we present a straightforward synthesis towards hierarchically structured, macroporous carbon/titania monoliths with ordered mesopores derived from resorcinol/formaldehyde monoliths and a glycolated titanium precursor. We demonstrate the influence of various reaction solvents, where diol-based media and the proportion of the catalyst seem to be essential in controlling spinodal decomposition, obtaining similar monolithic structures under different synthesis conditions. Based on these observations, we further homogeneously incorporated TiO₂ into the carbon structure by an in situ synthesis approach, obtaining structural features similar to pure carbon materials with surface areas of about 400 m² g^-1 , periodically arranged mesopores with a mean distance of 10-11 nm and cellular macroporosity.

Keywords: carbon; mesoporous materials; organic-inorganic composites; sol-gel processes.

Publication types

Research Support, Non-U.S. Gov't