Impact of Water and UV Irradiation on Nonwoven Polylactide/Natural Rubber Fiber

Polymers (Basel). 2021 Jan 31;13(3):461. doi: 10.3390/polym13030461.

Abstract

A nonwoven fiber made of polylactide/natural rubber with a rubber content from 0 to 15 wt.% was obtained by electrospinning from a solution. The water sorption test showed that the addition of natural rubber into the polylactide matrix did not significantly affect the degree of water absorption of the fibers, which was in the range of 48.9-50.6%. The melt flow rate only increased by 0.5 g/10 min at a content of 15 wt.% natural rubber. The thermal characteristics after 120 days of degradation in distilled water and UV irradiation (50 h) at a wavelength of 365 nm were determined using differential scanning calorimetry. Changes in the values of the phase transition temperatures and the degree of crystallinity were determined. It was determined that the fiber samples from all compositions retained the propensity for photo- and hydrolytic degradation.

Keywords: UV-irradiation; electrospinning; hydrolytic degradation; natural rubber; non-woven fiber; polylactide.