Enhanced Water Purification Performance of Ionic Liquid Impregnated Metal-Organic Framework: Dye Removal by [BMIM][PF6]/MIL-53(Al) Composite

Safiyye Kavak; Özce Durak; Harun Kulak; H Mert Polat; Seda Keskin; Alper Uzun

doi:10.3389/fchem.2020.622567

Enhanced Water Purification Performance of Ionic Liquid Impregnated Metal-Organic Framework: Dye Removal by [BMIM][PF₆]/MIL-53(Al) Composite

Front Chem. 2021 Jan 25:8:622567. doi: 10.3389/fchem.2020.622567. eCollection 2020.

Authors

Safiyye Kavak^{1

2}, Özce Durak^{1

3}, Harun Kulak^{1

3}, H Mert Polat^{1

2}, Seda Keskin^{1

3}, Alper Uzun^{1

3

4}

Affiliations

¹ Koç University TÜPRAS Energy Center (KUTEM), Koç University, Istanbul, Turkey.
² Department of Materials Science and Engineering, Koç University, Istanbul, Turkey.
³ Department of Chemical and Biological Engineering, Koç University, Istanbul, Turkey.
⁴ Koç University Surface Science and Technology Center (KUYTAM), Koç University, Istanbul, Turkey.

Abstract

We incorporated a water-stable ionic liquid (IL), 1-butyl-3-methylimidazolium hexafluorophosphate, [BMIM][PF₆], into a water-stable metal-organic framework (MOF), MIL-53(Al), to generate the [BMIM][PF₆]/MIL-53(Al) composite. This composite was examined for water purification by studying its capacity for methylene blue (MB) and methyl orange (MO) removal from aqueous solutions having either single dye or a mixture of both. Data illustrated that the removal efficiency and the maximum adsorption capacity of MIL-53(Al) were increased several times upon [BMIM][PF₆] incorporation. For instance, within 1 min, 10 mg of pristine MIL-53(Al) adsorbed 23.3% MB from 10 mg/L of MB solution, while [BMIM][PF₆]/MIL-53(Al) composite was adsorbed 82.3% MB in an identical solution. In the case of MO, 10 mg of pristine MIL-53(Al) achieved 27.8 and 53.6% MO removal from 10 mg/L of MO solution, while [BMIM][PF₆]/MIL-53(Al) composite removed 61.4 and 99.2% within 5 min and 3 h, respectively. Moreover, upon [BMIM][PF₆] incorporation, the maximum MB and MO adsorption capacities of the pristine MOF were increased from 84.5 to 44 mg/g to 204.9 to 60 mg/g, respectively. The adsorption of dyes in pristine MIL-53(Al) and [BMIM][PF₆]/MIL-53(Al) followed a pseudo-second-order kinetic model and a Langmuir isotherm model. In a mixture of both dyes, the IL/MOF composite showed a doubled MB selectivity after the IL incorporation. The composite was successfully regenerated at least two times after its use in water purification to remove MB, MO, and their mixtures. Infrared (IR) spectra indicated that the MB/MO adsorption occurs on [BMIM][PF₆]/MIL-53(Al) by electrostatic interactions, hydrogen bonding, and π-π interactions. These results showed that [BMIM][PF₆]/MIL-53(Al) composite is a highly promising material for efficient water purification.

Keywords: MOF; composite; dye removal; ionic liquid; water purification.