Investigation on Thermodynamic Equilibrium Conditions of Methane Hydrates in Multiphase Gas-Dominant Pipelines

Jai Krishna Sahith Sayani; Srinivasa Rao Pedapati; Zamzila Kassim; Bhajan Lal

doi:10.1021/acsomega.0c04204

Investigation on Thermodynamic Equilibrium Conditions of Methane Hydrates in Multiphase Gas-Dominant Pipelines

ACS Omega. 2021 Jan 22;6(4):2505-2512. doi: 10.1021/acsomega.0c04204. eCollection 2021 Feb 2.

Authors

Jai Krishna Sahith Sayani^{1

2}, Srinivasa Rao Pedapati¹, Zamzila Kassim^{3

4}, Bhajan Lal^{2

3}

Affiliations

¹ Department of Mechanical Engineering, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, Perak 32610, Malaysia.
² CO2 Research Centre (CO2RES), Universiti Teknologi PETRONAS, Bandar Seri Iskandar, Perak 32610, Malaysia.
³ Chemical Engineering Department, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, Perak Darul Ridzuan 32610, Malaysia.
⁴ PETRONAS Research Sdn Bhd, Kawasan Institusi Bangi, Lot 3288 & 3289 Off Jalan Ayer Itam, Kajang, Selangor 43000, Malaysia.

Abstract

The estimation of thermodynamic equilibrium conditions of methane hydrates in the presence of crude oil based on experiments is shown in this research work. This pipeline system replicated the gas-dominant multiphase transmission pipelines at deep-sea regions. An experimental study is done by the usage of a Raman gas hydrate reactor. The pressure was maintained in the range of 3-8 MPa for the experimental study. The water cut is kept constant throughout the system as 30%. Initially, the experimental setup is calibrated by using carbon dioxide gas. Then, methane hydrates are formed with and without crude oil. The methane hydrates that are created without the presence of crude oil are validated with simulation that is performed using CSMGEM, PVTSIM software, and literature data. Then, the thermodynamic conditions are found for the methane hydrate formation in the presence of crude oil with an addition of a 15% oil cut to the system. From these results, the phase behavior of a multiphase system is evaluated. The formation of methane hydrates in the system was found to be affected by the presence of an additional oil phase that exhibited an inhibition behavior. This research validates all the multiphase systems that contain similar hydrocarbon and gas compositions.