Hexavalent chromium reduction by gallic acid

Abstract

Cr(VI) is widely used in industry and often large quantities have been accidently or due to lack of precautions released at the environment. The presence of high concentrations of Cr(VI) in waste streams causes concern due to its toxicity and solubility. However the Cr(III) is a useful micronutrient in human diet. The reduction of Cr(VI) to Cr(III) is a promising technology for a clean environment. Polyphenols are commonly found in plants and they are considered as strong natural antioxidants. In this study the reduction of hexavalent to trivalent chromium using gallic acid (GA), a polyhydroxyphenolic compound, was evaluated. The effect of pH, temperature, and Cr(VI) concentration on the kinetics of Cr(VI) reduction by GA were examined by conducting batch tests. It was found that reduction of Cr(VI) by GA is a rapid reaction under mild acidic conditions. Reduction was found to follow a 2nd order kinetics with respect to Cr(VI) concentration in the pH range 3-5. The results of the present study indicated that the treatment of contaminated waters with initial concentration of Cr(VI) 100 μΜ by gallic acid, below the environmental limit of 0.96 μM, required 20 min at pH 3 and 40 min at pH 4. At higher pH a different reduction mechanism seems to prevail and the required time for Cr(VI) reduction was approximately 10 h at pH 5 and 42 h at pH 6. The increase of temperature25 °C to 35 °C, at pH 6, was slightly accelerated the reaction.

Keywords: Gallic acid; Hexavalent chromium; Polyphenols; Reduction kinetics.