In this work, powdered Calotropis gigantea seedpods were characterized and used as biosorbents of methylene blue dye from aqueous solution. FT-IR spectroscopy demonstrated functional groups characteristics of cellulose. Steric exclusion chromatography donated an average molecular weight of 230 kg/mol of the biopolymer. The polymolecularity index value (1.95) proved the good homogeneity of the polysaccharide. Scanning electron microscopy features displayed a homogenous morphology and porous structure. X-ray diffraction patterns showed peaks characteristics of cellulose and non-cellulose compositions. Thermogravimetric analysis/differential thermal analysis displayed exothermal decompositions at 316.9 °C and 456 °C. The maximum biosorption capacity of methylene blue was 88.36 mg/g at pH = 6, time = 60 min, and T = 21 °C. The level was comparable to some other studied agricultural wastes. The adsorption mechanism followed pseudo-second-order and Freundlich models. As it is abundant, available, low-cost, and easily recovered from solution, C. gigantea seedpods could be used as an effective biomaterial for the removal of organic pollutants from contaminated waters. Novelty statement: An abundant, available, and low-cost Calotropis gigantea seedpod was used, for the first time, as an effective biomaterial for the biosorption of organic pollutants. The biosorption level was found to be comparable to some other agricultural wastes studied previously in the literature.
Keywords: Biosorption; Calotropis gigantea; SEC; SEM; XRD; methylene blue; seedpods.