A Simple and Scalable Approach for Fabricating High-Performance Superparamagnetic Natural Cellulose Fibers and Papers

Carbohydr Polym. 2021 Mar 15:256:117425. doi: 10.1016/j.carbpol.2020.117425. Epub 2020 Nov 23.

Abstract

This study introduces a new combined method of wood impregnation and chemical pulping processes leading to the production of superparamagnetic cellulose fibers with a magnetic nanoparticle-free outer surface. First, magnetic wood chips (MWCs) were prepared by in situ synthesizing of magnetite (Fe3O4) nanoparticles during the wood impregnation process. The MWCs were then converted into magnetic fibers by kraft pulping. The results showed that the resulting magnetic fibers had an outer surface comparable to that of non-magnetic fibers while showing superparamagnetic behavior. The XRD results confirmed that the in situ synthesized magnetic nanoparticles were magnetite. Papers made from the new type of magnetic cellulose fibers had much more desirable tensile properties, appearance, and printability than papers made from conventional magnetic cellulose fibers, comparable to those made from non-magnetic fibers.

Keywords: Fe(3)O(4) nanoparticles; Magnetic paper; interface quality; nanoparticles-free surface; superparamagnetic; tensile properties.

MeSH terms

  • Cellulose / chemistry*
  • Colorimetry / methods
  • Ferrosoferric Oxide* / chemistry
  • Magnetic Iron Oxide Nanoparticles / chemistry*
  • Magnetics*
  • Microscopy, Electron, Scanning
  • Nanoparticles / chemistry*
  • Nanotechnology / methods
  • Particle Size
  • Populus
  • Spectroscopy, Fourier Transform Infrared
  • Temperature
  • Tensile Strength
  • Wood / chemistry*
  • X-Ray Diffraction

Substances

  • Cellulose
  • Ferrosoferric Oxide