Electrochemical behavior of aluminium anode in super-gravity field and its application in copper removal from wastewater by electrocoagulation

Abstract

Anodic passivation is a key problem to reduce the efficiency of electrocoagulation (EC) process. Super-gravity technology was introduced into EC process to enhance the treatment of heavy metal wastewater using pure aluminum electrode. The results showed that the removal ratio of Cu increased, and the cell voltage decreased with the increase of gravity coefficient, suggesting a promoting effect of super-gravity field on electrocoagulation process. Electrochemical behavior of aluminium anode in super-gravity field was analyzed by potentiodynamic polarization, cyclic voltammetry and electrochemical impedance spectroscopy. It was found that anodic polarization behavior of aluminium showed a typical characteristic of dissolution in super-gravity, rather than passivation in normal gravity. The type of anode dissolution changed from pitting corrosion to uniform corrosion in super-gravity field. The outer oxidized film of anode was thinning, and more Al³⁺ ions were released by anode dissolution, which was attributed to the super-gravity enhancement of the mass transfer process of Cl^- ions. In addition, X-ray diffraction and Fourier transform infrared spectroscopy indicated that the flocs generated in super-gravity field had amorphous and looser Al-O framework structure. As a result, the efficiency of EC process was improved by super-gravity.

Keywords: Aluminium anode; Dissolution; Electrocoagulation; Passivation; Super-gravity field; Wastewater.