Technical feasibility of biodiesel production from virgin oil and waste cooking oil: Comparison between traditional and innovative process based on hydrodynamic cavitation

Abstract

Biodiesel production calls for innovative solutions to turn into a competitive process with a reduced environmental impact. One of the process bottlenecks stands in the immiscibility of oil and alcohol as raw materials, so mixing process largely impacts the overall process cost. This process step, if carried out by using hydrodynamic cavitation, has the possibility to become a benchmark for large scale applications. In this paper a process analysis of biodiesel production scheme is developed starting from two different feedstocks, virgin oil and waste cooking oil. At the first the traditional process scheme has been simulated, in a second simulation, the reactor for the biodiesel production is interchanged with a hydrodynamic cavitation reactor. In the paper, the comparison between the traditional and innovative process by using life cycle costing approach has been presented, thus providing indications for industrial technological implementation coming from a professional tool for process analysis. It is worth noting that the introduction of hydrodynamic cavitation reduces of about 40% the energy consumption with respect to the traditional process. As regards the total treatment costs, when using virgin oil as feedstock, they were in the range 820-830 €/t (innovative and traditional process, respectively); while starting from waste cooking oil the costs decreased of about 60%, down to 290-300 €/t (innovative and traditional process, respectively).

Keywords: Biodiesel; Hydrodynamic cavitation; Life cycle costing; Process simulation; Recycling; Waste cooking oil.