Synthesis of layered double hydroxides with nitrate and its adsorption properties of phosphate

Abstract

In the present study, different ratios of layered double hydroxides (LDHs) were synthesized via co-precipitation method. The synthesized LDHs were characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), nitrogen adsorption-desorption analysis, point of zero charges (pH_pzc), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Phosphate adsorption performances were estimated by batch adsorption experiments; desorption hysteresis and adsorption mechanism were also investigated. The XRD, SEM and TEM results confirmed the multilayer structure of the synthesized LDHs. The pseudo-second-order kinetic model and the Freundlich model describe the adsorption behavior of LDHs best. The maximum adsorption capacity is 185.86 mg-KH₂PO₄/g for Mg₂Al-NO₃ LDH. When the dosage of LDHs was greater than 2 g/L, the phosphorus content in the solution decreased from 30 mg-P/L to 0.077 mg-P/L after adsorption by Mg₂Al-NO₃ LDH. All the results reveal that Mg₂Al-NO₃ LDH is a potential adsorbent for removing phosphate from aqueous solution.