Quantitative analysis of the synergistic effect of Au nanoparticles on SnO2-rGO nanocomposites for room temperature hydrogen sensing

Phys Chem Chem Phys. 2021 Jan 28;23(3):2377-2383. doi: 10.1039/d0cp05701k.

Abstract

Hydrogen detection devices based on gold-tin oxide/reduced graphene oxide (Au-SnO2/rGO) nanohybrids were fabricated by combining a hydrothermal method with sputter coating. The gas sensing performance of the Au-SnO2/rGO sensor was investigated under different concentrations of hydrogen from 0.04% to 1% at room temperature, which indicated a notable sensitive response even for 0.04% hydrogen. The activation energies of hydrogen adsorption/desorption were extracted via Arrhenius analysis which revealed the acceleration effect of gold dopants. This acceleration led to a faster response and recovery during hydrogen sensing. The activation energy analysis provided a more comprehensive understanding on the gas sensing mechanism. A hydrogen detection handheld device is demonstrated by integrating the sensor chip with a portable digital meter for direct readout of test results.